11 Oct 2008 10:00 AM

Natural Fingerprints In Coal Used To Track Mercury Emissions



University of Michigan researchers have developed a new tool that uses natural "fingerprints" in coal to track down sources of mercury polluting the environment.

The research is published in the online issue of the journal Environmental Science & Technology.

Mercury is a naturally occurring element, but some 2000 tons of it enter the environment each year from human-generated sources such as incinerators, chlorine-producing plants and coal-burning power plants. Mercury is deposited onto land or into water, where microorganisms convert some of it to methylmercury, a highly toxic form that builds up in fish and the animals that eat them. In wildlife, exposure to methylmercury can interfere with reproduction, growth, development and behavior and may even cause death.

Effects on humans include damage to the central nervous system, heart and immune system. The developing brains of young and unborn children are especially vulnerable.

"There has been a lot of controversy about how much mercury is coming from different types of industrial activities, compared to natural sources, but it has been difficult to figure out the relative contributions," said co-author Joel Blum, the John D. MacArthur Professor of Geological Sciences and a professor of ecology and evolutionary biology. "And even if you can determine how much of it is coming from natural versus human sources, there's still the question of how much is from global sources, such as coal-fired power plants overseas, and how much is being produced and deposited locally."

For the past eight years, Blum and co-workers have been trying to develop a way of reading mercury fingerprints in coal and other sources of mercury. The hope was that they could then find those same fingerprints in soil and water bodies, much as a detective matches a suspect's fingerprints to those found at a crime scene, and use them to figure out exactly what the sources of mercury pollution are in certain areas.

"For some time, we weren't sure that it was going to be technically possible, but now we've cracked that nut and have shown significant differences not only between mercury from coal and, say, metallic forms of mercury that are used in industry, but also between different coal deposits," Blum said…